Synthesis And Characterization Of Hetero Binuclear Complex Consisting Ni (II) And Cs(I) From Caesium Salt Of Acetyl Salicylic Acid (ASPIRIN) And Nickel (II) Schiff Base N,N’–1,2–Ethylene Bis(Ortho-Hydroxyacetophenoniminato) Nickel (II) As Ligand
Author(s): Sanjay Kumar
Authors Affiliations:
Associate Professor, Department of Chemistry, Patna Science College,
Patna University, Patna, INDIA
DOIs:10.2015/IJIRMF/202610007 | Paper ID: IJIRMF202610007Abstract: In order to synthesize hetero-binuclear complex consisting Ni (II) and Cs(I), dibasic Ni (II) Schiff base N,N’–1,2–ethylenebis(ortho-hydroxyaceto phenoniminato) nickel(II) [NiEohacp] has been prepared from Nickel acetate and Schiff base (Eohacp) derived from Ethylene diamine and ortho-hydroxy acetophenone. This Ni (II) Schiff base [NiEohacp] has been used as ligand for complexation with Caesium salt of Acetyl salicylic acid (ASPIRIN) resulting in synthesis of the novel hetero binuclear complex [NiEohacpCsAp]. This synthesized hetero binuclear complex has been obtained in pure dark goldenrod crystalline solid. The structure elucidation of this synthesized hetero binuclear complex has been carried out using various physico-chemical techniques viz. Solubility, Elemental analysis, Magnetic property, Molar conductance measurement, UV-Visible and FT-IR spectroscopy. From the analysis of the data obtained the formula of the synthesized complex [NiEohacpCsAp] has been proposed as Where L = N,N’-1,2-ethylenebis(ortho-hydroxyacetophenoniminato) dianion and L’ = Acetyl salicylate with Square planar geometry about in the adduct.
Sanjay Kumar (2026); Synthesis And Characterization Of Hetero Binuclear Complex Consisting Ni (II) And Cs(I) From Caesium Salt Of Acetyl Salicylic Acid (ASPIRIN) And Nickel (II) Schiff Base N,N’–1,2–Ethylene Bis(Ortho-Hydroxyacetophenoniminato) Nickel (II) As Ligand, International Journal for Innovative Research in Multidisciplinary Field, ISSN(O): 2455-0620, Vol-12, Issue-10, Available on – https://www.ijirmf.com/